Raoult's Law
Raoult's Law: Overview
This topic covers concepts, such as, Raoult's Law, Raoult's Law for an Ideal Solution of Two Liquid Components, Lowering of Vapour Pressure & Calculation of Composition of Liquid and Vapour in a Solution etc.
Important Questions on Raoult's Law
For a binary ideal liquid solution, the variation in total vapour pressure versus composition of solution is given by which of the curves?

The vapour pressure of water is at . Now, calculate the vapour pressure of molar solution of a solute in it.

How we can prove that Raoult’s law as a special case of Henry’s law?

Raoult's law becomes a special case of Henry's law when . In this equation, is

Condition at which Raoult's law becomes a special case of Henry's law?

At , the vapour pressure of an ideal solution containing of liquid and of liquid is Hg. When of is added to this solution, the vapour pressure of the solution increases by . What are the respective vapour pressures (in mm ) of and in their pure states at ?

At , the vapour pressure of pure liquid 'A' is and that of pure liquid 'B' is If a mixture solution of 'A' and 'B' boils at and 1 atm pressure, the amount of 'A' in the mixture is:

The vapour pressures of pure benzene and toluene are 160 and 60mm Hg respectively. The mole fraction of benzene is vapour phase in contact with equimolar solution of benzene and toluene is

At benzene and toluene have a vapour pressure of and respectively. Assuming ideal behaviour of solution, calculate the mole fraction of benzene in a solution that boils at and .

A mixture of toluene and benzene forms a nearly ideal solution. Assume and to be the vapor pressures of pure benzene and toluene, respectively. The slope of the line obtained by plotting the total vapor pressure to the mole fraction of benzene is:

In the pressure vs. the mole fraction of benzene curves/lines shown below, the total vapour pressure of an ideal mixture of benzene and toluene will follow the curve/line.

Vapour pressure of benzene is . When of non-volatile solute is dissolved in benzene, benzene solution has vapour pressure . Calculate the molar mass of the solute in ( molar mass of benzene = ).

For a dilute solution containing of a non-volatile non-electrolyte solution in of water, the elevation in boiling point at pressure is Assuming the concentration of solute is much lower than the concentration of the solvent, the vapor pressure of the solution is ()

Two liquids and form an ideal solution. At , vapour pressure of the solution containing mole of and mole of is . At the same temperature, if mole of is further added to this solution, vapour pressure of the solution increases by . Vapour pressure (in ) of and in their pure states will be, respectively

The vapours pressure of pure components and are and respectively. Assuming a solution of these components obeys Raoult's law, the mole fraction of component in the vapours phase in equilibrium with a solution containing equimolecular of and is

of urea is dissolved in of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at is .

Which of the following units is most useful in relating concentration of solution with its vapour pressure?

When partial pressure of solvent in solution of non-volatile solute is plotted against its mole fraction, nature of graph is

Partial pressure of solvent (mole fraction) in solution of non-volatile solute (mole fraction) is given by equation,

If Two liquids A and B which form a non-ideal solution which obey the below equation as
Calculate the exact composition (by mole) when this mixture boils without change in composition at a definite temperature of an equimolar mixture of A and B is distilled, Where , are vapour pressures of A and B respectively mole fraction of B in liquid phase
